シルセスキオキサン

シルセスキオキサン(POSS : Polyhedral Oligomeric Silsesquioxane)

シルセスキオキサンは、有機物とセラミックの双方の特徴を併せ持つユニークなナノ材料です。

1.シリカ(SiO2)とシリコーン(R2SiO)のハイブリッドであるシルセスキオキサン(RSiO1.5)の量論的化合物 image1
2.大きさが多くのポリマーのセグメントやコイルと同じサイズである。

この特徴により、ポリマーの機械特性、耐熱性、耐火性の向上、密度の低減による粘性の減少など、様々な効果が期待できます。

Acrylate

製品名 CAS No. 構造
Acryloxypropyl polysilsesquioxane 1620202-27-8 All R = Acryloxypropyl
Acrylic polysilsesquioxane in 30% 20nm nanosilica 1620202-27-8 All R = Acryloxypropyl
Acryloxypropyl isobutyl polysilsesquioxane NA Acryloxypropyl : isobutyl = 1:7
Acrylicpropyl iso-Butyl polysilsesquioxane NA Acryloxypropyl : isobutyl = 1:1
Acrylpropyl iso-Octyl polysilsesquioxane NA Acryloxypropyl : isooctyl = 1:1
Acryloxypropylocty polysilsesquioxane NA Acryloxypropyl : octyl = 1:7
Acrylic PEG polysilsesquioxane NA Acryloxypropyl : PEG = 5:3
Acryloxypropylglycidyloxypropyl polysilsesquioxane NA Glycidyloxypropyl : Acryloxypropyl = 1:1

Alcohol

製品名 CAS No. 構造
trans-Cyclohexanediolisobutyl polysilsesquioxane 408439-48-3 3,4-Dihydroxy cyclohexylethyl : Isobutyl = 1:7
1,2-Propanediolisobutyl polysilsesquioxane 480439-49-4 1,2-Dihydroxypropoxy propyl : Isobutyl = 1:7

Amine

製品名 CAS No. 構造
Aminopropylisobutyl polysilsesquioxane 444315-15-5 Aminopropyl : isobutyl = 1:7
Aminopropylisooctyl polysilsesquioxane NA Aminopropyl : Isoctyl = 1:7
N-phenylaminopropyl polysilsesquioxane 1708993-28-5 All R = N-Phenylaminopropyl
70% N-phenylaminopropyl polysilsesquioxane in 30% PGMEA 1708993-28-5 All R = N-Phenylaminopropyl

Epoxide

製品名 CAS No. 構造
Epoxycyclohexylethyl polysilsesquioxane 187333-74-0 All R =Epoxycyclohexylethyl
70% Epoxycyclohexylethyl polysilsesquioxane in 30% PGMEA 187333-74-0 All R =Epoxycyclohexylethyl
70% Epoxycyclohexylethyl polysilsesquioxane in 30% diallyletherbisphenol A 187333-74-0 All R =Epoxycyclohexylethyl
70% Epoxycyclohexylethyl polysilsesquioxane in 30% Cycloaliphatic epoxy diluent 187333-74-0 All R =Epoxycyclohexylethyl
70% Epoxycyclohexylethyl polysilsesquioxane in 30% Cyclopentanone 187333-74-0 All R =Epoxycyclohexylethyl
Glycidyl polysilsesquioxane 68611-45-0 All R = Glycidiloxypropyl
50% Glycidyl polysilsesquioxane in 50% PGMEA 68611-45-0 All R = Glycidiloxypropyl
Glycidyl polysilsesquioxane in 30% 20nm nanosilica 68611-45-0 All R = Glycidiloxypropyl
Acryloxypropylglycidyloxypropyl polysilsesquioxane NA Glycidyloxypropyl : Acryloxypropyl = 1:1
Glycidyloxypropylphenyl polysilsesquioxane NA Glycidyloxypropyl : Phenyl= 1:1
Cyclohexylepoxy Glycidyl polysilsesquioxane NA Glycidyloxypropyl : Epoxycyclohexylethyl = 1:1
Epoxycyclohexylethyl iso-Butyl polysilsesquioxane NA Epoxycyclohexylethyl : isobutyl = 1:1
Epoxycyclohexylethyl iso-Octyl polysilsesquioxane NA Epoxycyclohexylethyl : isooctyl= 1:1
Cyclohexylethylepoxy isoOctyl polysilsesquioxane NA Epoxycyclohexylethyl : isooctyl= 3:1
Cyclohexylethylepoxy PEG polysilsesquioxane NA Epoxycyclohexylethyl : PEG= 3:1
Glycidyl iso-Butyl polysilsesquioxane NA Glycidyloxypropyl : isobutyl = 1:1
Glycidyl iso-Octyl polysilsesquioxane NA Glycidyloxypropyl : isooctyl = 1:1
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 1:1
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 1:3
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 3:1
Glycidyl Methacryl PEG polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl : PEG = 3:3:2
Glycidyl PEG polysilsesquioxane NA Two R = Glycidoxypropyl
Other all R = Methoxy PEG group
Glycidyl PEG polysilsesquioxane NA Glycidyloxypropyl : PEG = 5:3

Fluoroalkyl

製品名 CAS No. 構造
(Heptadecafluorooctyl)ethyl polysilsesquioxane NA All R = (Heptadecafluorooctyl)ethyl
Trifluoropropyl Methacrylpropyl polysilsesquioxane NA Trifluoropropyl :Methacryloxypropyl = 5:3
Methacrylpropyl Trifluoropropyl iso-Octyl PEG polysilsesquioxane NA Methacryloxypropyl : Trifluoropropyl : isooctyl : PEG = 1:1:1:1

PEGs

製品名 CAS No. 構造
MethoxyPEG polysilsesquioxane NA All R = PEG
MethoxyPEG isooctyl POSS 2171462-48-7 PEG : isooctyl = 1:3
PEG epoxycyclohexylethyl polysilsesquioxane NA Two R = Methoxy PEG group
Other all R = Epoxycyclohexylethyl
Glycidyl Methacryl PEG polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl : PEG = 3:3:2
Glycidyl PEG polysilsesquioxane NA Two R = Glycidoxypropyl
Other all R = Methoxy PEG group
Glycidyl PEG polysilsesquioxane NA Glycidyloxypropyl : PEG = 5:3
Acrylic PEG polysilsesquioxane NA Acryloxypropyl : PEG = 5:3
Methacrylpropyl Trifluoropropyl iso-Octyl PEG polysilsesquioxane NA Methacryloxypropyl : Trifluoropropyl : isooctyl : PEG = 1:1:1:1
Methacryl PEG polysilsesquioxane NA Two R = Methacryloxypropyl
Other all R = Methoxy PEG group
Methacryloxypropyl PEG polysilsesquioxane NA Methacryloxypropyl : PEG = 3:1
Methacryloxypropyl PEG polysilsesquioxane NA Three R = Methoxy PEG group
Other all R = Methacryloxypropyl

Silane

製品名 CAS No. 構造
Octasilane polysilsesquioxane 125756-69-6 All R = Dimethylsilaneoxy
Trisilanoloctyl polysilsesquioxane NA Three Si = Active silanol
Other all R = Octyl

Methacrylate

製品名 CAS No. 構造
Methacrylpropylisobutyl polysilsesquioxane 307531-94-8 Methacryloxypropyl : isobutyl = 1:7
Methacrylpropyl iso-Butyl polysilsesquioxane NA Methacryloxypropyl : isobutyl = 1:1
Methacryloxypropyl iso-Butyl polysilsesquioxane NA Methacryloxypropyl : isobutyl = 1:3
Methacryloxypropyl isooctyl polysilsesquioxane NA Methacryloxypropyl : isooctyl = 1:7
Methacrylpropyl iso-Octyl polysilsesquioxane NA Methacryloxypropyl : isooctyl = 1:1
Methacryloxypropyl iso-Octyl polysilsesquioxane NA Methacryloxypropyl : isooctyl = 1:3
Methacryloxypropyl ooctyl polysilsesquioxane NA Methacryloxypropyl : octyl = 1:7
Methacryloxypropyl polysilsesquioxane 160185-24-0 All R = Methacryloxypropyl
Methacrylic polysilsesquioxane in 30% 20nm nanosilica 160185-24-0 All R = Methacryloxypropyl
Alpha Methacryl polysilsesquioxane NA All R = Methacryloxymethyl
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 1:1
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 1:3
Glycidyl Methacryl polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl = 3:1
Glycidyl Methacryl PEG polysilsesquioxane NA Glycidyloxypropyl : Methacryloxypropyl : PEG = 3:3:2
Trifluoropropyl Methacrylpropyl polysilsesquioxane NA Trifluoropropyl :Methacryloxypropyl = 5:3
Methacrylpropyl Trifluoropropyl iso-Octyl PEG polysilsesquioxane NA Methacryloxypropyl : Trifluoropropyl : isooctyl : PEG = 1:1:1:1
Methacryl PEG polysilsesquioxane NA Two R = Methacryloxypropyl
Other all R = Methoxy PEG group
Methacryloxypropyl PEG polysilsesquioxane NA Methacryloxypropyl : PEG = 3:1
Methacryloxypropyl PEG polysilsesquioxane NA Three R = Methoxy PEG group
Other all R = Methacryloxypropyl

Molecular silica

製品名 CAS No. 構造
Dodecaphenyl polysilsesquioxane 18923-59-6 All R = Phenyl
Octaisooctyl polysilsesquioxane 190732-67-3 All R = Isoctyl
Octaisobutyl polysilsesquioxane 221326-46-1 All R = Isobutyl
OctaTMA polysilsesquioxane 69667-29-4 All R = Tetramethylammoniumoxy
Octaphenyl polysilsesquioxane 5256-79-1 All R = Phenyl
Methyl polysilsesquioxane NA All R = Methyl
Octyl polysilsesquioxane NA All R = Octyl
Dodecyl polysilsesquioxane NA All R = Dodecyl

Silanol

製品名 CAS No. 構造
Trisilanolisobutyl polysilsesquioxane 307531-92-6 Active silanol : isobutyl = 3:5
Trisilanolisooctyl polysilsesquioxane 444619-08-3 Active silanol : isooctyl = 3:5
Trisilanolooctyl polysilsesquioxane NA Active silanol : octyl = 3:5
Trisilanolphenyl polysilsesquioxane 444315-26-8 Active silanol : phenyl = 3:5
Poly(Phenylsilsesquioxane) : oligomer of Trisilanolphenyl polysilsesquioxane NA contains Active silanol and phenyl

Thiol

製品名 CAS No. 構造
Mercaptopropylisooctyl polysilsesquioxane NA Mercaptopropyl : isooctyl = 1:7

Olefins

製品名 CAS No. 構造
Vinyl iso-Octyl polysilsesquioxane 2126117-68-7 Vinyl : isoctyl = 7:1